The pick of the bunch was a stunning free kick for Chasetown's second goal after Cater's first goal followed in a rebound.
Liam Kirton scored the third after getting to the ball ahead of the keeper and coolly firing home under pressure from defenders.
Cater made it 4-1 passing the ball home from inside the box and netted his fourth and Chasetown's fifth from the spot.
Chasetown’s lineup:
1. Jack Atkinson
2. Alex Melbourne
3. Ricky Bridge
4. Tom Urwin
5. Ryan Wynter
6. James Askey
7. Danny Campbell
8. Brad Carr
9. Liam Kirton
10. Will Whieldon
11. George Cater
Subs
Joe Brown for Ricky Bridge, 30
Sam Tonks for Brad Carr, HT
Owen Nolan for Danny Campbell, HT
Curtis Pond for Jack Atkinson, 70
Ryan Stewart for Will Whieldon, 70